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Tetrachlorethylene
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Tetrachlorethylene

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Technical characteristics
  • BrandМэйджор Хим
  • Country of manufactureRussia
Description
TECHNICAL SPECIFICATION

tetrachlorethylene

Identification of a product 


Name of a product: Tetrachloroethylene

Identification of a product: Tetrachlorethylene

Systematic name: 1,1,2,2-tetrakhloreten

Tetrachlorethylene (tetrachloroethylene) — colourless liquid with a pungent smell, organochlorine solvent. Finds broad application in a dry-cleaner and degreasing of metals.

CAS No.: 127-18-4

Molecular weight: 165.83g/mol

Chemical formula: C2Cl4

Physical properties

Tetrakhloretilennegoryuch, it is inexplosive and does not self-ignite. It we will dissolve in the majority of organic solvents. With some solvents tetrachlorethylene forms azeotropny mixes .

Chemical properties

Tetrachlorethylene is the steadiest connection from all chlorderivatives of ethane and ethylene . It is steady against hydrolysis and promotes corrosion less, than other chlorine-containing solvents.

Name Technical specification Standard
Appearance Colourless, transparent liquid, without mechanical impurity and without stratifying Q/NBJH02-2013
Chroma (Pt-Co), ≤ 15
Density (20 °C) (g/cm3) 1.620-1.628
Purity of % (m/m) ≥ 99.9
Moisture of % (m/m) ≤ 0.005
PH 7.5-9.0
Alkalinity as NaOH, % ≤ 0.003
Stability (Corrosion copper loss), mg/cm2 ≤ 0.50
The rest after evaporation, % ≤ 0.005
Residual smell No

Application

• as the inert solvent capable to dissolve many organic substances. In this quality it finds application in processes of dry cleaning of linen (dry-cleaner);

• for degreasing of metal and other surfaces in mechanical engineering and instrument making;

• when processing photopolymeric printed circuit boards - by production of needles to disposable syringes;

• is parts for washout of paints;

• as intermediat by production of azonosberegayushchy hladon;

• as intermediat when receiving trikhloruksusny acid;

• in the textile and woodworking industry

CERTIFICATE OF QUALITY

Supplier: LLC MEYDZHOR HIM

Producer: NINGBO JUHUA CHEMICAL&SCIENCE CO., LTD.

PRODUCTION: TETRACHLORETHYLENE NUMBER NBJHJL-13-J-0
Date of selection of a sample 2016-01-26 Selection of a sample Barrel of 200 kg
Date of the analysis 2016-01-26 Standard Q/NBJH 02-2013
Party No. 041160124 Expiration date 24000.00 kg
Name Technical specification Result Standard
Appearance Colourless, transparent liquid, without mechanical impurity and without stratifying Corresponds Q/NBJH 02-2013
Chroma (Pt-Co), 15 10
Density (20 °C) (g/cm3) 1.620-1.628 1.625
Purity of % (m/m) ≥ 99.9 99.94
Moisture of % (m/m) ≤ 0.005 0.0016
PH 7.5-9.0 8.98
Alkalinity as NaOH, % ≤ 0.003 0.0004
Stability (Corrosion copper loss), mg/cm2 ≤ 0.50 0.05
The rest after evaporation, % ≤ 0.005 0
Residual smell No No

Expiration date: 3 years from the date of production.

Material safety data sheet

tetrachlorethylene

1. Identification of a product 


1.1. Identification of a product:

Name of a product: tetrachloroethylene

Identification of a product: tetrachlorethylene

Registration number of substance: 01-2119475329-28-0002 


1.2. The corresponding identified types of use of substance or mix and the recommended restrictions on use:

ES1: production of substance 


ES2: use as auxiliary product 


ES3: production use in dry cleaning 


ES4: professional use in dry cleaning 


ES5: production use when cleaning surfaces

ES6: production use in the heat carrier 


ES7: professional use in the cleaning cars and copying

ES8: distribution and packing

1.3. Information on the supplier: LLC INROIL

1.4. Information on the producer: NINGBO JUHUA CHEMICAL&SCIENCE CO., LTD.

1.5. Phone of the emergency service: no

2. Description of dangers

2.1. Classification of substance or mix

2.2. Marking

Attention 


Causes irritation of skin. Can cause allergic reaction. Can cause drowsiness and weakness. It is suspected of carcinogenicity. It is toxic for an organism with long adverse effect. Not to use all security measures are not taken yet. To avoid hit in environment. To use personal means of protection.

At hit on skin: to wash out a large amount of water with soap.

At inhalation: to bring the victim to fresh air, to leave alone. To ask for medical care.

CAS: 127-18-4

Identification number: 602-028-00-4

Contents: tetrachlorethylene 


Obligatory notes:

product density: 1,623 g/cm3 (20 °C);

general maintenance of VOC: 28,0-32,0% of hm. 


Additional information:

2.3. Other dangers

3. Structure/information on ingredients

Substance definition: tetrachlorethylene

CAS No.: 127-18-4 


Contents: 99,9%

4. First aid

4.1. Description of first aid

If you ail, immediately see a doctor

At inhalation: Bring the victim to fresh air. To see a doctor at the complicated breath.

At contact with skin: To take off the polluted clothes, to wash out the damaged site a large amount of warm water (30-32 °C) as it is possible more intensively. Ask for medical care.

At contact with eyes: To immediately wash out eyes under a water stream, as long as possible, but it is not less than 20 minutes. To ask for medical care and to continue washing of eyes.

At hit inside: To carefully rinse a mouth water. Not to cause vomiting. To call the doctor and to show him the material safety data sheet.

4.2. The most important symptoms

4.3. Description of special treatment: it is not revealed

5. Fire prevention

5.1. Fire extinguishing means

Fire extinguishing means: not fire-dangerous means

Fire extinguishing means which it is necessary to avoid: water stream of a high pressure

5.2. The dangers arising when using substance or mix. Burning of dangerous products can have negative effect on respiratory system. 


5.3. Council at the pozharotusheniiyena to prevent spread of fire without the protective clothes and means protecting breath.

6. Merypo to elimination of casual floods

6.1. Means of personal protection, the protective equipment and emergency measures to Use clothes, to secure eyes, hands

6.2. Ecological safety to Avoid hit in waste pipes / on the earth or in ground waters

6.3. Methods and materials for cleaning to Use a sorbent (sand). To get rid of material in special capacities for combustion of the chlorinated hydrocarbon. 


6.4. Reference to other sections

7. Address and storage 


7.1. Precautionary measures

Before use to study the instruction. To provide good airing in a working zone. In time to work not to eat food, not to drink, not to smoke.

7.2. Conditions of safe storage, including incompatible to Store far from ignition sources, separately from other substances, it is preferable in the new containers which are densely closed. In the Place of storage there has to be a box with first aid; drinking water. To prevent foreign intervention.

7.3. Features of end use

8. Influence control, protection of personnel

8.1. Control parameters

Tetrachloroethylene: PEL of 250 mg/m3 NKP-P of 750 mg/m3

8.2. Control over influence

Local influence is recommended

8.2.1 Professional control of emissions 


Protection of airways: various filters, the A+B type, it is necessary to dress where there can be organic vapors and sour gas. To use the offered means of protection.

Protection of hands: protective PVC gloves 


Protection of the eye/person: Safe points or protective board 


Protection of skin: to wear factory clothes, shoes

8.2.2 Control over emissions in environment

9. Physical and chemical properties 


9.1. Information on the main physical and chemical properties

Form: liquid 


Color: colourless 


Smell: sweetish

RN: not ionizing substance 


Boiling temperature: 121,1 °C 


Melting temperature:-22,4 °C 


Ignition temperature: it is not revealed 


Explosive properties: it is not explosive 


Acid properties: it is not defined 


Relative density: 1,623 (20 °C) 


Pressure para:1,87 kPa (20 °C) 


Solubility: 


Solubility in water: 0,2 (20 °C) 


Decomposition coefficient (n-oktanol / water): it is not defined

Self-ignition temperature: it is not defined 


Viscosity: it is not defined 


Density is couple: it is not defined

9.2. Other information:

Miscibility: it is not defined

Fat solubility: it is not limited

Groups of gas: it is not defined

10. Stability and reactivity

10.1 Reactivity

10.2 Chemical stability

10.3 Possibility dangerous reactions ̆

10.4 Conditions which it is necessary to avoid:

Without stabilizer this product decays, forming acid substances, especially chloride hydrogen.

10.5 Incompatible materials: are not revealed

10.6 Dangerous products of decomposition:

Chloride hydrogen. Evaporation/air can create phosgene where UF-radiation is possible.

11. Toxicological information 


11.1. Information on toxicological effect Acute toxicity:

2629 (merckkataloge 1999/2000)

The irritating effect on skin:

Irritation of eyes: 


Hypersensibility:

Mutagenicity: cancerogenic category 3

Reproductive toxicity:

Other information:

Steam inhalation can cause suffocation, fatigue, irritation of eyes, intoxication. Can cause violation of work of a liver after long contact with substance.

12. Ecological information 


12.1. Toxicity 


LC50 (96 h, fish, mg/l): it is not defined 


EC50 (48 h, water flea, mg/l): it is not defined 


IC50 (72 h, seaweed, mg/l): 


Other dangers 


Not to allow a product to get on the earth and to ground waters. In case of flood to address to the relevant institution.

12.2. Firmness and disintegration: it is not defined

12.3. Bio-accumulation potential

12.4. Manifestation in environment

12.5. Results of PBT and vPvB of an assessment

12.6. Other effects

13. Recycling 


13.1. Ways of processing of waste 


Danger of category N, code of danger 07 01 03. It has to be removed in suitable capacity for dangerous wastes, equipped with devices for combustion of chloride hydrogen. The cleared metal packing can be used as secondary material, the left packings have to be buried or removed in suitable capacity for dangerous wastes

14. Transport information

Danger class: 6.1; group of packing: III

14.1. Danger to environment:

The substance polluting the marine environment

14.2. Special remarks on use:

EMS number: F-A, S-A

Other transport information: motor/railway transport, air, sea

14.3. Transportation according to Addition 2 MARPOL 73/78 and the IBC code.

15. The regulating information

The directive of Council 67/548/EEC of June 27, 1967 about rapprochement of laws, rules and administrative situation ̆, belonging to classification, packing and marking of dangerous substances.

Regulations (EC) of No 1907/2006 of the European Parliament and Council of December 18, 2006 about registration, estimates, permissions and restrictions of chemicals (REACH), creation of the European chemical agency, the amendment to the Directive

The directive 1999/45/EU of the European Parliament and Council of May 31, 1999 about rapprochement of laws, rules and administrative situation ̆ the member states concerning classification, packing and marking of dangerous preparations. 
 the Directive of Council 75/442/EEC of July 15, 1975 about waste. 


The directive of Council 91/689/EEC of December 12, 1991 about dangerous wastes. 


The directive of Council 94/55/EU of November 21, 1994 about rapprochement of the legislation of the states - members concerning transportation of dangerous freights by the motor transport.

The directive of Council 96/49/EU of July 23, 1996 about rapprochement of the legislation of the states - members in connection with transportation of dangerous freights by rail.

The directive of Council 1999/13/EU of March 11, 1999 about restriction of emissions flying organic connection ̆ in connection with use of organic solvents in some kinds of activity and installations.

The directive of Council 89/391/EEC of June 12, 1989 about introduction of the measures promoting improvement of safety and health of workers on a workplace.

Regulations of the Commission (EC) of No 453/2010 of May 20, 2010 making changes to Regulations (EC) of No 1907/2006 of the European parliament and Council for registration, an assessment, authorization and restriction of chemicals (REACH).

16. Additional information

H315 Causes irritation of skin. 


H317 Can cause allergic reaction of skin. 


H336 Can cause drowsiness and dizziness. 


H351 Presumable influence causes cancer

H411 Toxic for water organisms with long-term consequences.

P202 do not undertake so far all precautionary measures were not read and understood.

P273 to Avoid hit in environment.

P281 use of means of individual protection according to requirements.

P302 + P352 IF ON SKIN: To wash out a large amount of water and soap.

P304 + P340 AT INHALATION: To take out the victim on fresh air and to provide it full rooms ̆ convenient for breath. 


P308 + P313 concern CASE: To see for the council / help a doctor.

P391 collecting floods.

To Store P405 under the lock.

To Remove with P501 contents / container in...

R40 Limited proofs of cancerogenic effect.

R51/53 Toxic for water organisms, can cause long-term dangerous impact on the water environment.

To Store S2 in the place, inaccessible for children. 


S23 not to inhale gases / smokes/couple / sprays ̆ (the corresponding formulations have to be specified by the manufacturer). 


S23A not to inhale fumes. 


S36/37 to Wear suitable protective clothes and gloves. 
 to Avoid S61 hits in environment. To refer to special instructions / the material safety data sheet. 


Revision of a dannykhizmeneniye are brought according to Regulations (EU) No 1272/2008 and the Resolution No 453/2010 (EU).

17. OTHER INFORMATION

The LLC INROIL company provides information which is contained in the present document is conscientious, but does not make any statements concerning its completeness or accuracy. This document is intended only as the management.

These data are based on our today's level knowledge ̆, but are not a guarantee of properties of a product and is not valid contractual legal relationship ̆. Information given above is considered exact and provides the fullest information now. Nevertheless, we do not give any a guarantee ̆ concerning sale of a product or any other to a guarantee ̆, obvious or implied, in relation to such information, and we do not bear any responsibility as a result of its use. Users have to make own researches for determination of suitability of information for their specific goals.

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